The world's smallest 'lauburu'

2025 Mar 19

The study, led by Shanghai Jiao Tong University and the Hefei National Laboratory, with the participation of Ikerbasque researchers at DIPC Ricardo Ortiz and Thomas Frederiksen, used tunneling microscopy and spectroscopy to demonstrate that nanographenes can couple with metal centres to enhance quantum magnetism. One of the molecules observed in this study resembles the shape of the ‘lauburu’, a traditional Basque symbol

The world's smallest 'lauburu'
One of the observed molecules resambles the shape of the Basque 'lauburu'

In recent years, magnetic interactions in nanographenes have been a major focus in quantum materials research. A new study published in National Science Review takes this exploration further by investigating how the unpaired π-electrons of nanographenes interact with magnetic metal atoms (iron and cobalt). This novel approach provides new fresh insights into π-d exchange coupling, a key mechanism for spintronics and quantum computing.

The study, led by researchers from Shanghai Jiao Tong University and Hefei National Laboratory, used scanning tunneling microscopy and spectroscopy to reveal a magnetic exchange interaction of 9 meV (Fe) and 5 meV (Co). These findings were further supported by quantum chemistry calculations by Ricardo Ortiz and Thomas Frederiksen, researchers from the Donostia International Physics Center (DIPC) and Ikerbasque, the Basque Foundation for Science.

By demonstrating how nanographenes can couple with metal centers to enhance quantum magnetism, this research opens new pathways for engineering metal-organic frameworks with tunable magnetic properties. The results mark an important step towards tailor-made molecular magnets, with implications for next-generation quantum technologies and nanoscale electronics.

Beyond its scientific significance, the study has an unexpected local connection: one of the observed molecules takes the shape of a lauburu, the traditional Basque symbol. Given the precision of the imaging techniques, this is likely to be the smallest lauburu ever observed—a fitting coincidence for a discovery involving DIPC, right in the heart of the Basque Country!

Publication reference

Deng-Yuan Li, Yuqiang Zheng, Ricardo Ortiz, Bing-Xin Wang, Yashi Jiang, Bingkai Yuan, Xin-Yu Zhang, Can Li, Liang Liu, Xiaoxue Liu, Dandan Guan, Yaoyi Li, Hao Zheng, Canhua Liu, Jinfeng Jia, Thomas Frederiksen, Pei-Nian Liu, Shiyong Wang
Magnetic exchange interaction between unpaired π- and d-electrons in nanographene-metal coordination complexes
National Science Review, Volume 12, Issue 4 (2025)
DOI: 10.1093/nsr/nwaf033